Pesticide residues in difficult matrices

Pesticides-tomato

Complex matrices is not a problem anymore! Validated, efficient and reliable method by GCxGC-TOFMS.

To be more confident reporting pesticide residue results you need a fit for purpose methods as well as robust instrumentation. LECO helps you to implement a solution for the analysis of pesticide residues in difficult food samples. The combination of QuEChERS sample preparation with large volume PTV-GCxGC-TOFMS analysis, provides a solution with unrivalled performance, sensitivity, speed and robustness.

GCXGC-TOFMS benefits

 

Challenge the matrix

  • Unsurpassed GCxGC separation
  • Spectral deconvolution


Trust in your results

  • Full mass spectra by TOFMS for confident analyte identification
  • High quality mass spectral deconvolution in ChromaTOF software
  • Low LODs thanks to cryofocusing and matrix separation


Increase your throughput

  • Simplified sample prep even for complex matrices
  • No SIM or MS-MS windows construction – more analytes per run
  • Easily add new pesticides
  • No need for ion source cleaning
  • Optional Gerstel Automated Liner Exchange (ALEX) for uninterrupted operation
  • Automated GCxGC-TOFMS data processing and fast data review


Find more

  • Find unexpected contaminants by unrivalled non-target search capabilities

Method summary :

  • QuEChERS sample preparation according to EN 15662:2008
  • Sample preparation: 20 min/sample
  • 47 min GC-MS turnaround time for 150 pesticides in a single run
  • Performance criteria comply to SANCO/12495/2011
  • LOQs 2- 8 ppb for all pesticides and comply to EU MRL for baby food
  • Method validated for fruits, vegetables, grains and oil in an accredited EU national reference laboratory
GCxGC plot 1

Analysis of grain extract spiked with 150 pesticides: Unrivalled analyte by analyte and analyte by matrix separation


The GCxGC-TOFMS is fully automated system for unattended operation. No need to construct SIM or MS-MS windows. Full mass spectra provided by time-of-flight mass spectrometer combined with high quality mass spectral deconvolution enables confident analyte identification. Synchronized with Automated Peak Find, mass spectra for each analyte is automatically extracted free of interferences from the system background, matrix background, and coeluting analytes. Structured work flow of LECO ChromaTOF brand software automates the process from fully automated data acquisition, identification of target pesticides, its quantification toward to final summary reports.

GCxGC-pic2

Detection of flutriafol in grain at 4 ppb. Matrix (linoleic acid) interferes with flutriafol peak and its quantification masses. Thanks to second dimension separation and mass spectral deconvolution, the peak is separated from interference and can be reliably detected, identified and quantified.

 

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